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研究队伍

姓名：	孙伟	性别：	男
学科类别：	物理化学	职务：
学历：	博士	职称：	研究员
电话：	0931-4968278	传真：	0931-8277088
电子邮件：	wsun@licp.cas.cn
通讯地址：	中国甘肃省兰州市天水中路18号

简　　历：

孙伟，男，博士，研究员，博士生导师，羰基合成与选择氧化国家重点实验室副主任。1998年本科于曲阜师范大学，2003年于vic115维多利亚获理学博士学位。2003年获德国洪堡奖学金，在德国慕尼黑工业大学无机化学研究所进行博士后研究。2005年底回国，并入选中国科学院“人才计划”，在vic115维多利亚羰基合成与选择氧化国家重点实验室开展仿生催化、均相催化及纳米催化等领域的研究工作。已在Acc. Chem. Res., J. Am. Chem. Soc., Angew. Chem. Int. Ed.及《催化学报》等国内外重要学术期刊发表研究论文100余篇。现为《有机化学》编委、《催化学报》青年编委。

研究方向：

仿生催化、均相催化及纳米催化等

代表性研究工作：基于高活性非血红素生物酶活性中心，课题组发展了一系列手性四氮配体及其锰铁配合物，实现了烯烃、烷烃的高效不对称氧化反应（Bioinspired Manganese and Iron Complexes for Enantioselective Oxidation Reactions: Ligand Design, Catalytic Activity, and Beyond. Acc. Chem. Res. 2019, 52, 2370-2381.）。最近，Amgen公司基于我们发展的高效非血红素锰催化烯烃不对称环氧化反应（Manganese Catalysts with C1-Symmetric N4 Ligand for Enantioselective Epoxidation of Olefins, Chem. Eur. J., 2012, 18, 6750-6753.），实现了卡非佐米关键中间体手性环氧酮的工业生产，锰催化剂用量低至0.04 mol% （Org. Process Res. Dev. 2020, 24, 490-499.）。相关工作也充分展现了非血红素锰催化剂的高活性。

获奖及荣誉：

1.德国洪堡奖学金
2.甘肃省自然科学二等奖（2007）

承担科研项目：

国家自然科学基金、中科院重要方向性项目

代表论著：

1.Wei Sun*, Qiangsheng Sun, Bioinspired Manganese and Iron Complexes for Enantioselective Oxidation Reactions: Ligand Design, Catalytic Activity, and Beyond. Acc. Chem. Res. 2019, 52, 2370-2381.
2.Bin Qiu, Daqian Xu, Qiangsheng Sun, Jin Lin, Wei Sun*, Manganese-Catalyzed Asymmetric Oxidation of Methylene C-H of Spirocyclic Oxindoles and Dihydroquinolinones with Hydrogen Peroxide. Org. Lett. 2019, 21, 618-622.
3.Junyi Du, Chengxia Miao, Chungu Xia, Yong-Min Lee, Wonwoo Nam*, Wei Sun*, Mechanistic Insights into the Enantioselective Epoxidation of Olefins by Bioinspired Manganese Complexes: Role of Carboxylic Acid and Nature of Active Oxidant. ACS Catal. 2018, 8, 4528-4538.
4.Bin Qiu, Daqian Xu, Qiangsheng Sun, Chengxia Miao, Yong-Min Lee, Xiao-Xi Li, Wonwoo Nam*, Wei Sun*, Highly Enantioselective Oxidation of Spirocyclic Hydrocarbons by Bioinspired Manganese Catalysts and Hydrogen Peroxide. ACS Catal. 2018, 8, 2479-2487.
5.Wenfang Wang, Qiangsheng Sun, Chungu Xia, Wei Sun*, Enantioselective epoxidation of olefins with hydrogen peroxide catalyzed by bioinspired aminopyridine manganese complexes derived from L-proline, Chin. J. Catal. 2018, 39, 1463-1469.
6.Chengxia Miao, Xiao-Xi Li, Yong-Min Lee, Chungu Xia, Yong Wang, Wonwoo Nam*, and Wei Sun*，Nonheme Manganese Complex-Catalyzed Oxidation and Oxidative Kinetic Resolution of Secondary Alcohols by Hydrogen Peroxide, Chem. Sci. 2017, 8, 7476.
7.Chengxia Miao, Xingbin Yan, Daqian Xu, Chungu Xia, Wei Sun*, Bioinspired Manganese Complexes and Graphene Oxide Synergistically Catalyzed Asymmetric Epoxidation of Olefins with Aqueous Hydrogen Peroxide. Adv. Syn Catal. 2017, 359, 476-484.
8.Chengxia Miao, Bin Wang, Yong Wang, Chungu Xia, Yong-Min Lee, Wonwoo Nam*, and Wei Sun*，Proton-Promoted and Anion-Enhanced Epoxidation of Olefins by Hydrogen Peroxide in the Presence of Nonheme Manganese Catalysts, J. Am. Chem. Soc. 2016, 138, 936 – 943.
9.Duyi Shen, Bin Qiu, Daqian Xu, Chengxia Miao, Chungu Xia, Wei Sun*, Enantioselective Epoxidation of Olefins with H2O2 Catalyzed by Bioinspired Aminopyridine Manganese Complexes, Org. Lett. 2016, 18, 372–375.
10.Chengxia Miao, Hanqing Zhao, Quanyi Zhao, Chungu Xia，Wei Sun*，NHPI and Ferric Nitrate: a Mild and Selective System for Aerobic Oxidation of Benzylic Methylenes，Catal. Sci. Technol. 2016, 6, 1378-1383.
11.Zhenbei Zhang, Qiangsheng Sun, Daqian Xu, Chunggu Xia, Wei Sun*, Directly halogenative dearomatization of 2-naphthols by NXS (X = Cl, Br) in water, Green Chem. 2016,18, 5485–5492.
12.Zhenbei Zhang, Qiangsheng Sun, Chungu Xia, and Wei Sun*, CO2 as a C1 Source: B(C6F5)3-Catalyzed Cyclization of o-Phenylene-diamines to Construct Benzimidazoles in the Presence of Hydrosilane. Org. Lett. 2016, 18, 6316-6319.

社会任职：

个人网页：

/rcjy/brjh/bairensw/