时间：2018年1月26日上午9点 

　　地点：理化楼三楼会议室 

　　学术报告一 

　　Self-Assembly Methodologies for Construction of Metallo-Supramolecular Architectures 

　　报告人：Yi-Tsu Chan (詹益慈) 副教授 

　　台湾大学 化学系 

　　报告摘要： 

　　The self-assembly processes through coordination chemistry for bottom-up construction of nanoscale organic-inorganic objects and patterns have received tremendous attention not only owing to their aesthetic architectures but also to their potential applications in drug delivery, optoelectronics, sensors, magnetic materials, catalysis, etc. To achieve precise assembly of predesigned building units into the predictable and desired structures still remains a great challenge because numerous physical and chemical factors may have a significant influence on the assembling behavior. To overcome the obstacles, our research team devoted our efforts to developing new methodology for coordination-driven self-assembly. Recently, we achieved a complementary complexation pair of terpyridine-based ligands with Cd¹¹ ions.'¹ The selective coordination mechanism was elucidated by tandem mass spectrometry and ¹H NMR titration experiments, indicating that the auxiliary ion-dipole interactions derived from the dimethoxyphenyl substituents facilitate the spontaneous heteroleptic complex formation under ambient conditions. In order to reduce kinetic errors in a multicomponent self-assembly process, this high-fidelity self-recognition pair was further applied to construction of two multicomponent metallo-supramolecular structures, i.e., an enlarged triangle and a bilayered isogonal hexagon.'¹² Their structural characterization was carefully done by NMR spectroscopy, traveling wave ion-mobility mass spectrometry (TWIM-MS), single-crystal X-ray analysis (for the enlarged triangle only), AFM, and TEM. On the other hand, another complementary ligand pair with Zn¹¹ ions was designed and synthesized.^M This ligand pair was utilized in preparation of metallo-supramolecular rod-coil P3HT-/j-PEO diblock copolymers. The self-assembled nanostructures of the resultant amphiphilic copolymers in solution were investigated and their dynamic features were demonstrated by reversible complexation-decomplexation reactions. The presented supramolecular methodology highlights the merits of complementary metal-ligand coordination, and offers a new approach to precisely engineering assembled nanostructures. These and other aspects of metallo-supramolecular assemblies will be discussed. 

　　1.    Wang, S.-Y.; Fu, J.-H.; Liang, Y.-P.; He, Y.-J.; Chen, Y.-S.; Chan, Y.-T. J. Am. Chem. Soc. 2016, 138, 3651. 

　　2.    Fu, J.-H.; Lee Y.-H.; He, Y.-J.; Chan Y.-T. Angew. Chem. Int. Ed. 2015, 54, 6231. 

　　3.    He, Y.-J.; Tu, T.-H.; Su, M.-K.; Yang, C.-W.; Kong, K. V.; Chan, Y.-T. J. Am. Chem. Soc. 2017, 139, 4218. 

报告人简介： 

　　詹益慈 副教授。2000 年臺灣大學化學系學士；2002 年臺灣大學化學系碩士；2010  年美國艾克朗大學高分子科學系博士；2010-2012  年東京大學日本學術振興會特別研究員；2012-2017  年任臺灣大學化學系助理教授；2017 年迄今任臺灣大學化學系副教授。研究领域：金屬配位超分子組裝方法學的開發、超分子組裝體質譜分析；功能性金屬配位超分子共聚物的設計與合成及其在溶液與固態的組裝行為。 

　　学术报告二 

　　螺旋手性聚异腈的可控制备及应用于手性分离 

　　报告人：吴宗铨 教授 

　　合肥工业大学化学与化工学院 

    报告人简介：

   吴宗铨，2001年本科毕业于安徽师范大学化学与材料科学学院，随后在中科院上海有机所攻读研究生，2006年获得博士学位。2006年10月至2009年12月，在日本名古屋大学从事博士后研究工作，历任日本学术振兴会(JSPS)外国人特别研究员博士后、日本科学技术振兴机构 (JST/ERATO)研究员博士后。2010年1月至2010年11月在美国德克萨斯大学奥斯汀分校做博士后。2011年受聘为合肥工业大学化学与化工学院教授、博士生导师。2016年获得国家自然科学基金委优秀青年科学基金项目。近年来，主要从事螺旋手性高分子及其共聚物可控合成及应用的研究工作，探索光学活性高分子材料在不对称催化、对映体分离及手性自组装等领域中的应用。发表学术论文70余篇，包括J. Am. Chem. Soc., Macromolecules, Chem. Commun.等。担任《中国化学快报》第一届青年编委，J. Am. Chem. Soc., Macromolecules (top 150 reviewers of 2015), Chem. Commun., ACS Macro Lett., Polym. Chem.等国际期刊审稿人。研究方向：手性高分子。